Effect of Vinyl and Silicon Monomers on Mechanical and Degradation Properties of Bio-Degradable Jute-Biopol® Composite

Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Composites of jute fabrics (Hessian cloth) and Biopol® were prepared by compression molding process. Three types of Biopol® (3-hydroxbutyrate-co-3-hydroxyvalarate) such as D300G, D400G and D600G, depending on the concentration of 3-hydroxyvalarate (3HV) in 3-hydroxbutyrate (3HB) were taken for this purpose. Mechanical properties such as tensile strength (TS), bending strength (BS), elongation at break (Eb) and impact strength (IS) of the jute-Biopol® composites were studied. It was found that the composite with D400G produced higher mechanical properties in comparison to the other two types of Biopol®. To increase mechanical properties as well as interfacial adhesion between fiber and matrix, 2-ethyl hydroxy acrylate (EHA), vinyl tri-methoxy silane (VMS) and 3-methacryloxypropyl tri-methoxy silane (MPS) were taken as coupling agents. Enhanced mechanical properties of the composites were obtained by using these coupling agents. Biopol® D400G composites showed the highest mechanical properties. Among the coupling agents EHA depicts the highest increase of mechanical properties such as tensile strength (80%), bending strength (81%), elongation at break (33%) and impact strength (130%) compared pure Biopol. SEM investigations demonstrate that the coupling agents improve the interfacial adhesion between fiber and matrix. The surface of the silanized jute was characterized by FTIR and found the deposition of silane on jute fiber was observed. Soil degradation test proved that the composite prepared with EHA treated jute exhibits better degradation properties in comparison to pure Biopol®

Aluminum alloys with improved strength

Mechanical strength and stress corrosion of new BAR and 7050 alloys that include Zn instead of Cr have been studied and compared with those of 7075 aluminum alloy. Added mechanical strength of new alloys is attributed to finer grain size of 5 to 8 micrometers, however, susceptibility to stress corrosion attack is increased

Changes in the mechanical properties of dermal sheep collagen during in vitro degradation

The changes in tensile strength, elongation at break, and high strain modulus of dermal sheep collagen (DSC) during in vitro degradation using bacterial collagenase were studied. The changes in mechanical properties were compared with the change in weight of the samples as a function of degradation time. DSC was crosslinked with either glutaraldehyde (GA) or hexamethylene diisocyanate (HMDIC). During degradation, the changes in mechanical properties of the N-DSC, H-DSC or G-DSC samples were more pronounced than the changes in the weight of the samples. Of the mechanical properties studied, the tensile strength was most susceptible to degradation of the DSC samples. After 2.5 h, N-DSC samples had lost only 55% of their initial weight, but the samples had no tensile strength left. Similar results were obtained for H-DSC, which retained no tensile strength after 24 h degradation, whereas only 45% of the initial weight was lost. G-DSC lost 3.5% of its weight after 24 h degradation, but only 25% of the initial tensile strength remained

Determination of wood strength properties through standard test procedures

In this study a review of existing recognised standards for wood mechanical testing was conducted. This review considers tensile, compressive, bending and shear test methodologies from a range of sources. In addition, values for wood mechanical properties were obtained through controlled experimentation using a universal material testing machine. Selected standard procedures were used to obtain wood strength properties both along and across the grain. These consist of a three point bending procedure used to evaluate the wood strength across the grain and a longitudinal shear procedure used to evaluate the wood strength along the grain. Strength properties obtained through controlled experimentation are compared to values available in existing literature with little discrepancy

Development of a high strength Al-Mg2Si-Mg-Zn based alloy for high pressure die casting

A high strength Al-Mg2Si-Mg-Zn based alloy has been developed for the application in high pressure die casting to provide improved mechanical properties. The effect of various alloying elements on the microstructure and mechanical properties including yield strength, ultimate tensile strength and elongation of the alloy was investigated under the as-cast and heat-treated conditions. The typical composition of the high strength alloy has been optimised to be Al-8.0wt%Mg2Si-6.0wt%Mg-3.5wt%Zn-0.6wt%Mn (Al-11.0wt%Mg-2.9wt%Si-3.5wt%Zn-0.6wt%Mn) with unavoidable trace impurities. The mechanical properties of the alloy were enhanced by a quick solution treatment followed by ageing treatment. The improved tensile properties were at a level of yield strength over 300MPa, the ultimate tensile strength over 420MPa and the elongation over 3% assessed using international standard tensile samples made by high pressure die casting. The microstructure of the die-cast alloy consisted of the primary α-Al phase, Al-Mg2Si eutectics, AlMgZn intermetallics and α-AlFeMnSi intermetallics under the as-cast condition. The AlMgZn intermetallic compound was dissolved into the Al-matrix during solution treatment and subsequently precipitated during ageing treatment for providing the effective improvement of the mechanical properties.The financial support is gratefully acknowledged for the Engineering and Physical Sciences Research Council (EPSRC) (Project number: EP/I038616/1), Technology Strategy Board (TSB) (Project number: 101172) and Jaguar Land Rover (JLR), United Kingdom

Controlled intermittent interfacial bond concept for composite materials

Concept will enhance fracture resistance of high-strength filamentary composite without degrading its tensile strength or elastic modulus. Concept provides more economical composite systems, tailored for specific applications, and composite materials with mechanical properties, such as tensile strength, fracture strain, and fracture toughness, that can be optimized

The resistance of selected high strength alloys to embrittlement by a hydrogen environment

Selected high strength iron base and cobalt base alloys were resistant to degradation of mechanical properties in a one atmosphere hydrogen environment at ambient temperature. These alloys were strengthened initially by cold working which produced strain induced martensite and fcc mechanical twins in an fcc matrix. Heat treatment of the cobalt base alloy after cold working produced carbide precipitates with retention of an hcp epsilon phase which increased the yield strength level. High strength alloys can be produced which have some resistance to degradation of mechanical properties by a hydrogen environment under certain conditions

Thermal treatment and mechanical properties of aluminum-2021

Mechanical properties, after thermal treatments, are summarized for sheet and plate of copper-rich, high-strength, heat-treatable aluminum-2021. The alloy is quench sensitive, quench rate and variations in aging affect corrosion behavior. Aging effects on yield strength, tensile strength, and elongation of sheet and plate are compared